Good read app note from Texas Instruments about configuring unused op amps on multi amp chips. Link here (PDF)
Multi-channel operational amplifiers (op amps) are often implemented in circuits that do not require the use of all channels. Undesired behavior in an unused amplifier channel can negatively impact system performance, as well as the performance of the channels in use. To avoid degradation of both the op amp and system performance, the unused op amp channels must be configured properly.